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Enzymatic phosphory...
Enzymatic phosphorylation of cellulose nanofibers to new highly-ions adsorbing, flame-retardant and hydroxyapatite-growth induced natural nanoparticles
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- Bozic, Mojca (author)
- Faculty of Mechanical Engineering, Institute for Engineering Materials and Design, University of Maribor
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- Liu, Peng (author)
- Luleå tekniska universitet,Materialvetenskap
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- Mathew, Aji P. (author)
- Luleå tekniska universitet,Materialvetenskap
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- Kokol, Vanja (author)
- Faculty of Mechanical Engineering, Institute for Engineering Materials and Design, University of Maribor
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(creator_code:org_t)
- 2014-05-10
- 2014
- English.
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In: Cellulose. - : Springer Science and Business Media LLC. - 0969-0239 .- 1572-882X. ; 21:4, s. 2713-2726
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- This study confirms the enzyme-mediated phosphorylation of cellulose nanofibers (CNF) by using hexokinase and adenosine-5’-triphosphate (ATP) in the presence of Mg-ions, resulting in a phosphate group’s creation predominantly at C-6-O positioned hydroxyl groups of cellulose monomer rings. A proof-of-concept is provided using 12C CPMAS, 31P MAS NMR, ATR-FTIR and XPS analyzing methods. The degree of substitution is determined for the first time by ATR-FTIR spectroscopy being in a correlation with XPS and potentiometric titration results. From the thermal degradation measurements using TGA, the C-6-O phosphorylation was found to noticeably prevent the CNF derivatives from weight loss in the pyrolysis process, thus, providing them flame-resistance functionality. Furthermore, phosphorylation significantly enhanced adsorption capacity of Fe3+ ions making them interesting for fabrication of biobased filters and membranes. Finally, the biomimetic growth of Ca-P crystals (hydroxyapatite) in simulated body fluid was characterized by SEM and showing further practicability for biomedical materials.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Industriell bioteknik -- Biomaterial (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Industrial Biotechnology -- Bio Materials (hsv//eng)
Keyword
- Trä och bionanokompositer
- Wood and Bionanocomposites
Publication and Content Type
- ref (subject category)
- art (subject category)
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