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Investigation of ma...
Investigation of mandelic acid bonding on Pirkle type chromatographic stationary phases by Raman spectroscopy
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- Horváth, E. (author)
- Hungarian Academy of Sciences
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- Kristóf, J. J. (author)
- University of Veszprem
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- Frost, R. L. (author)
- Queensland University of Technology
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- Rintoul, L. (author)
- Queensland University of Technology
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- Rédey, Á. (author)
- University of Veszprem
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- Forsling, Willis (author)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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(creator_code:org_t)
- 2000
- 2000
- English.
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In: Journal of Chromatography A. - 0021-9673 .- 1873-3778. ; 893:1, s. 37-46
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The bonding of mandelic acid enantiomers has been studied on benzene-leucine, dinitrobenzene-leucine and dinitrobenzene-phenylalanine type chiral stationary phases connected to zeolite A supports. The π-donor, π-acceptor and H-bonding interactions responsible for diastereomer pair formations can be studied under quasi in situ chromatographic conditions by Fourier transform Raman and surface enhanced Raman spectroscopic techniques. Structural differences between diastereomer pairs result in observable spectral differences at a phase load of approx. 50%. It was shown that the decreasing π-acceptor character of the phase is associated with its increasing capability of H-bond formation. Correlating spectral data to chromatographic results it can be concluded that, in addition to H-bonding as well as to π-donor-π-acceptor interactions, steric hindrances due to bulky moieties of either the stationary phase or the analyte molecules are of importance in successful separations.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Chemistry of Interfaces
- Gränsytors kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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