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Synthesis, structur...
Synthesis, structural and multinuclear natural abundance (C-13, P-31, Pt-195) CP/MAS NMR studies of crystalline O,O '-dialkyldithiophosphate platinum(II) complexes
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- Ivanov, Alexander V. (author)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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- Lutsenko, I. A. (author)
- Russian Adademy of Sciences
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- Ivanov, M. A. (author)
- Russian Adademy of Sciences
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- Gerasimenko, A. V. (author)
- Russian Adademy of Sciences
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- Antzutkin, Oleg (author)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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(creator_code:org_t)
- 2008
- 2008
- English.
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In: Russian journal of coordination chemistry. - 1070-3284 .- 1608-3318. ; 34:8, s. 584-593
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Platinum(II) O,O'-dicyclohexyl dithiophosphate [Pt{S2P(O-cyclo-C6H11)(2)}(2)] (I) and platinum(II) O,O'-diisopropyl dithiophosphate [Pt{S2P(O-iso-C3H7)(2)}(2)] (II) complexes were obtained and studied by solidstate C-13, P-31, and Pt-195 CP/MAS NMR spectroscopy. The dithiophosphate (Dtph) ligands in molecular structure I were found to be coordinated by platinum in S,S'-bidentate fashion to form the planar chromophore [PtS4] (single-crystal X-ray diffraction data). For complex II, a new alpha-form (alpha-II) was obtained and identified by P-31 MAS NMR spectroscopy. The P-31 chemical shift anisotropy delta(aniso) and the asymmetry parameter eta of the P-31 chemical shift tensor were calculated from the whole MAS spectra.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Chemistry of Interfaces
- Gränsytors kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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