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Transient kinetic a...
Transient kinetic analysis of the oxidative dehydrogenation of propane
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- Creaser, Derek (author)
- Luleå tekniska universitet
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- Andersson, B. (author)
- Chalmers University of Technology, Department of Chemical Reaction Engineering
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- Hudgins, R.R. (author)
- Department of Chemical Engineering, University of Waterloo
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- Silveston, P.L. (author)
- Department of Chemical Engineering, University of Waterloo
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(creator_code:org_t)
- Elsevier BV, 1999
- 1999
- English.
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In: Journal of Catalysis. - : Elsevier BV. - 0021-9517 .- 1090-2694. ; 182:1, s. 264-269
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Oxidative dehydrogenation of propane was studied using various transient techniques. Results support a redox mechanism in which propane reduces the catalyst, which is reoxidized by gas-phase oxygen. Only lattice oxygen participates in propene formation. Desorbable oxygen is a major source of poor selectivity, although lattice oxygen also causes total oxidation. Consequently, propene selectivity in the absence of gas-phase O2is superior to co-feed, steady-state selectivity at the same propane conversion. Propene selectivity is further improved by increasing the degree of catalyst reduction.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
Keyword
- Chemical Technology
- Kemisk teknologi
Publication and Content Type
- ref (subject category)
- art (subject category)
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