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Co-pyrolysis Behavior and Char Structure Evolution of Raw/Torrefied Rice Straw and Coal Blends

He, Qing (author)
East China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, Shanghai 200237, Peoples R China
Guo, Qinghua (author)
East China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, Shanghai 200237, Peoples R China
Ding, Lu (author)
Luleå tekniska universitet,Energivetenskap
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Gong, Yan (author)
East China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, Shanghai 200237, Peoples R China
Wei, Juntao (author)
East China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, Shanghai 200237, Peoples R China
Yu, Guangsuo (author)
East China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, Shanghai 200237, Peoples R China
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 (creator_code:org_t)
2018-11-30
2018
English.
In: Energy & Fuels. - Washington : American Chemical Society (ACS). - 0887-0624 .- 1520-5029. ; 32:12, s. 12469-12476
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Combination of biomass and coal for energy production is conducive to the sustainable development of society and a clean-energy future. This study investigates co-pyrolysis behavior of raw/torrefied rice straw and coal blends. Mild torrefaction (250 degrees C) and severe torrefaction (300 degrees C) were taken into consideration. Samples of five mixing ratios were tested by thermogravimetric analyzer, and the resulting chars were characterized by Raman spectroscopy and SEM-EDS. The results show that co-pyrolysis had little effect on char yields. Decomposition rate curves showed two distinct peaks for raw/mildtorrefied rice straw and coal blends, and the reaction rate was enhanced below 380 degrees C. However, only one peak appeared for severely torrefied rice straw blended with coal. During co-pyrolysis, the secondary pyrolysis of coal around 700 degrees C was inhibited, and the graphitization degree of biomass char increased, while the crystalline structure of coal char was poorly organized. The activation energy of mixtures also changed in different pyrolysis stages.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Maskinteknik -- Energiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Mechanical Engineering -- Energy Engineering (hsv//eng)

Keyword

thermal-behavior
thermogravimetric characteristics
raman-spectroscopy
biomass
kinetics
torrefaction
wood
Energiteknik
Energy Engineering

Publication and Content Type

ref (subject category)
art (subject category)

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By the author/editor
He, Qing
Guo, Qinghua
Ding, Lu
Gong, Yan
Wei, Juntao
Yu, Guangsuo
About the subject
ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Mechanical Engin ...
and Energy Engineeri ...
Articles in the publication
Energy & Fuels
By the university
Luleå University of Technology

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