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Pt and Co3O4 suppor...
Pt and Co3O4 supported on ceria and zirconia for the catalytic reduction of N2O in the presence of CO
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- Khan, Zakir Zaman (author)
- Catalysis and Nanomaterials Lab 27, Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan
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- Khan, Inayat Ali (author)
- Luleå tekniska universitet,Kemiteknik,Catalysis and Nanomaterials Lab 27, Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan
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- Khan, Ishtiaq (author)
- Catalysis and Nanomaterials Lab 27, Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan
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- Wattoo, Muhammad Hamid Sarwar (author)
- Ishfaq Ahmad Research Laboratories Complex, R-Block, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad, Pakistan
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- Badshah, Amin (author)
- Catalysis and Nanomaterials Lab 27, Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan
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(creator_code:org_t)
- Elsevier, 2019
- 2019
- English.
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In: Solid State Sciences. - : Elsevier. - 1293-2558 .- 1873-3085. ; 98
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Ceria (CeO2) and zirconia (ZrO2) supported Pt and Co3O4-based nanocatalysts were synthesized and characterized by different instrumental techniques. The catalysts redox properties and active surface areas were evaluated using temperature-programmed reduction (TPR), temperature-programmed oxidation (TPO) and H2-pulse chemisorption, respectively. The catalysts were tested for the thermal oxidation of carbon monoxide (CO), reduction of nitrous oxide (N2O) and conversion of N2O/CO mixture (1:1 vol%) . In catalytic tests, Pt–Co3O4/CeO2 (10:10%) oxidized CO up to 100% at 25 °C and Co3O4/CeO2 (20%) reduced N2O up to 90% at 320 °C. Moreover, Pt–Co3O4/CeO2 (10:10%) converted N2O/CO mixture to N2/CO2 up to 90% at about 210 °C. The low-temperature catalytic activity of Pt–Co3O4/CeO2 (10:10%) for CO oxidation and N2O/CO mixture redox conversion were attributed to uniform particle size, metals and support proper combination and electron interaction.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Ceria
- N2O reduction
- Nanocatalysts
- H2-pulse chemisorption
- Active surface area
- Chemistry of Interfaces
- Gränsytors kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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