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Clathrate Formation...
Clathrate Formation of Bis(diethyldithiocarbamato)pyridinezinc(II) and Bis(diethyldithiocarbamato)pyridinecopper(II) with Benzene by EPR, High-Resolution Solid-State 13C and 15N NMR, and X-ray Crystallography
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- Ivanov, Alexander V. (author)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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- Kritikos, M. (author)
- Arrhenius Laboratory, University of Stockholm
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- Lund, A. (author)
- University of Linköping
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- Antzutkin, Oleg (author)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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- Rodina, T.A. (author)
- Amur Institute of Integrated Research, Far East Division, Russian Academy of Sciences
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(creator_code:org_t)
- 1998
- 1998
- English.
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In: Russian Journal of Inorganic Chemistry. - 0036-0236 .- 1531-8613. ; 43:9, s. 1368-1376
- Related links:
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https://urn.kb.se/re...
Abstract
Subject headings
Close
- The structures of the clathrates of bis(diethyldithiocarbamato)pyridinezinc(H) and-copper(II) with benzene were studied by EPR, high-resolution solid-state 13C and 15N NMR, and X-ray crystallography. The geometry of the coordination polyhedra in the clathrates M(EDtc)2· Py · C6H6is close to trigonal-bipyramidal. Two short M-S bonds and the M-N bond form the equatorial plane, and two long M-S bonds point toward the axial positions. For the magnetically diluted copper(II) clathrate, the hyperfine structure can be observed at low temperatures due to the nitrogen atom of pyridine, which is associated with the contribution of the dz2orbital to the ground-state wave function of the unpaired electron. The 13C and 15N NMR signals were assigned.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Chemistry of Interfaces
- Gränsytors kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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