Search: onr:"swepub:oai:DiVA.org:ltu-90488" > The beauty of being...
Fältnamn | Indikatorer | Metadata |
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000 | 06047naa a2200637 4500 | |
001 | oai:DiVA.org:ltu-90488 | |
003 | SwePub | |
008 | 220502s2022 | |||||||||||000 ||eng| | |
009 | oai:DiVA.org:umu-194834 | |
009 | oai:DiVA.org:uu-477762 | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-904882 URI |
024 | 7 | a https://doi.org/10.1016/j.jcat.2022.04.0292 DOI |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-1948342 URI |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4777622 URI |
040 | a (SwePub)ltud (SwePub)umud (SwePub)uu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Khasevani, Sepideh G.u Luleå tekniska universitet,Materialvetenskap,Luleå University of Technology, Department of Engineering Sciences and Mathematics, Luleå, Sweden,Luleå Univ Technol, Dept Engn Sci & Math, S-98187 Luleå, Sweden.4 aut0 (Swepub:ltu)sepgho |
245 | 1 0 | a The beauty of being complex: Prussian blue analogues as selective catalysts and photocatalysts in the degradation of ciprofloxacin |
264 | 1 | b Elsevier,c 2022 |
338 | a print2 rdacarrier | |
500 | a Validerad;2022;Nivå 2;2022-05-11 (sofila) | |
520 | a We investigate the performance of four Prussian blue analogues (PBAs) as catalysts for the selective degradation of ciprofloxacin in water, under both dark and illumination conditions. We show that no light is actually needed to induce a selective degradation of the molecular target, while light irradiation spurs the process, without, however, resulting in the commonly reported photolysis-supported breaking down. We present a systematic characterization of the PBAs aiming at interpreting the catalytic outcomes in the light of a classic coordination chemistry analysis, empowered by the most recent findings in literature. We show that varying the transition metal binding the N atom of the cyanide bridge is key to promote photoinduced charge generation and transfer, which effectively disrupts the molecular target. The analysis of the materials before and after the irradiation with solar simulated light results in a change of the lattice parameters, indicating the possibility of a light-induced spin cross-over. | |
650 | 7 | a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng |
650 | 7 | a NATURVETENSKAPx Kemix Fysikalisk kemi0 (SwePub)104022 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Physical Chemistry0 (SwePub)104022 hsv//eng |
650 | 7 | a NATURVETENSKAPx Biologix Biofysik0 (SwePub)106032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Biological Sciencesx Biophysics0 (SwePub)106032 hsv//eng |
653 | a Prussian blue analogues | |
653 | a Ciprofloxacin degradation | |
653 | a Photocatalysis | |
653 | a Auto-catalytic reactions | |
653 | a Mössbauer spectroscopy | |
653 | a Engineering Materials | |
653 | a Materialteknik | |
653 | a Experimentell fysik | |
653 | a Experimental Physics | |
700 | 1 | a Nikjoo, Dariush,d 1977-u Luleå tekniska universitet,Materialvetenskap,Luleå University of Technology, Department of Engineering Sciences and Mathematics, Luleå, Sweden,Luleå Univ Technol, Dept Engn Sci & Math, S-98187 Luleå, Sweden.4 aut0 (Swepub:ltu)darnik |
700 | 1 | a Ojwang, Dickson O.,d 1985-u Uppsala universitet,Strukturkemi4 aut0 (Swepub:uu)dicoj366 |
700 | 1 | a Nodari, Lucau Dipartimento di Scienze Chimiche, Università degli Studi di Padova, 35131 Padova, Italy; Istituto di Chimica della Materia Condensata e di Tecnologie per l’Energia, ICMATE-CNR, 35127 Padova, Italy,Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy.;Ist Chim Mat Condensata & Tecnol Energia ICMATE-CN, Padua I-35127, Italy.4 aut |
700 | 1 | a Sarmad, Shokatu Umeå universitet,Kemiska institutionen,Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, SE-90871 Umeå, Sweden,Umeå Univ, Chem Biol Ctr, Dept Chem, Tech Chem, SE-90871 Umeå, Sweden.4 aut0 (Swepub:umu)shsa0039 |
700 | 1 | a Mikkola, Jyri-Pekkau Umeå universitet,Kemiska institutionen,Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, SE-90871 Umeå, Sweden; Industrial Chemistry & Reaction Engineering, John Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, Fl-20500 Åbo-Turku, Finland,Umeå Univ, Chem Biol Ctr, Dept Chem, Tech Chem, SE-90871 Umeå, Sweden.;Abo Akad Univ, John Gadolin Proc Chem Ctr, Ind Chem & React Engn, Biskopsgatan 8, FI-20500 Abo Turku, Finland.4 aut0 (Swepub:umu)jymi0001 |
700 | 1 | a Rigoni, Federicau Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, 30170 Venezia-Mestre, Italy,Foscari Univ Venice, Dept Mol Sci & Nanosyst, I-30170 Venice, Italy.4 aut |
700 | 1 | a Concina, Isabellau Luleå tekniska universitet,Materialvetenskap,Luleå University of Technology, Department of Engineering Sciences and Mathematics, Luleå, Sweden,Luleå Univ Technol, Dept Engn Sci & Math, S-98187 Luleå, Sweden.;Luleå Univ Technol, Dept Engn Sci & Math, Div Mat Sci, S-98187 Luleå, Sweden.4 aut0 (Swepub:ltu)isacon |
710 | 2 | a Luleå tekniska universitetb Materialvetenskap4 org |
773 | 0 | t Journal of Catalysisd : Elsevierg 410, s. 307-319q 410<307-319x 0021-9517x 1090-2694 |
856 | 4 | u https://doi.org/10.1016/j.jcat.2022.04.029y Fulltext |
856 | 4 | u https://umu.diva-portal.org/smash/get/diva2:1662792/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print |
856 | 4 | u https://uu.diva-portal.org/smash/get/diva2:1673049/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-90488 |
856 | 4 8 | u https://doi.org/10.1016/j.jcat.2022.04.029 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-194834 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-477762 |
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