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Kinetics study and performance evaluation of a hybrid choline-glycine/polyethylene glycol/water absorbent for CO2 separation

Chen, Yifeng (author)
Institute of Chemical Industry of Forest Products, CAF; National Engineering Laboratory for Biomass Chemical Utilization; Key and Open Laboratory of Forest Chemical Engineering, SFA; Key Laboratory of Biomass Energy and Material, Nanjing 210042, China; Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
Liu, Sida (author)
College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
Sun, Kang (author)
Institute of Chemical Industry of Forest Products, CAF; National Engineering Laboratory for Biomass Chemical Utilization; Key and Open Laboratory of Forest Chemical Engineering, SFA; Key Laboratory of Biomass Energy and Material, Nanjing 210042, China; Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
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Jiang, Jianchun (author)
Institute of Chemical Industry of Forest Products, CAF; National Engineering Laboratory for Biomass Chemical Utilization; Key and Open Laboratory of Forest Chemical Engineering, SFA; Key Laboratory of Biomass Energy and Material, Nanjing 210042, China; Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
Wang, Dong (author)
Sinopec Nanjing Research Institute of Chemical Industry Co., Ltd., Nanjing 210048, China
Yang, Zhuhong (author)
College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
Ji, Xiaoyan (author)
Luleå tekniska universitet,Energivetenskap
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 (creator_code:org_t)
Elsevier B.V. 2023
2023
English.
In: Separation and Purification Technology. - : Elsevier B.V.. - 1383-5866 .- 1873-3794. ; 304
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Thermodynamic and kinetic properties of absorbents are beneficial in evaluating their CO2 separation performance. In this study, the kinetic properties of CO2 in a hybrid choline-glycine/polyethylene glycol/water absorbent, including the liquid-side mass-transfer coefficient, enhancement factor, and reaction rate constant, were systematically determined through experimental measurements and data processing. Furthermore, an index referred to as “absorbility” was proposed to combine the kinetic properties determined in this study with the thermodynamic properties obtained in our previous study to evaluate the CO2 separation performance. Additionally, the regeneration performance of the hybrid absorbent was also conducted. The results show that the performance of the hybrid absorbent (30 wt% [Cho][Gly] + 10 wt% PEG200 + 60 wt% H2O) is comparable to that of aqueous monoethanolamine, and is thus promising for CO2 separation, considering its low regeneration temperature and low environmental impact.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Maskinteknik -- Energiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Mechanical Engineering -- Energy Engineering (hsv//eng)

Keyword

Absorbents
Absorbility
Carbon dioxide
Ionic liquids
Kinetics
Energiteknik
Energy Engineering

Publication and Content Type

ref (subject category)
art (subject category)

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