Search: onr:"swepub:oai:DiVA.org:ltu-95280" > Strain in Copper/Ce...
Fältnamn | Indikatorer | Metadata |
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000 | 05664naa a2200565 4500 | |
001 | oai:DiVA.org:ltu-95280 | |
003 | SwePub | |
008 | 230116s2023 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-952802 URI |
024 | 7 | a https://doi.org/10.1021/acsnano.2c084532 DOI |
040 | a (SwePub)ltu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Wang, Haibinu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China; Key Laboratory of Efficient Utilization of Low and Medium Grade Energy Ministry of Education, Tianjin University, Tianjin 300350, P. R. China4 aut |
245 | 1 0 | a Strain in Copper/Ceria Heterostructure Promotes Electrosynthesis of Multicarbon Products |
264 | c 2022-12-27 | |
264 | 1 | b American Chemical Society,c 2023 |
338 | a print2 rdacarrier | |
500 | a Validerad;2023;Nivå 2;2023-01-16 (joosat);Funder: National Natural Science Foundation of China (NSFC 51771132, 52204320). | |
520 | a Elastic strains in metallic catalysts induce enhanced selectivity for carbon dioxide reduction (CO2R) toward valuable multicarbon (C2+) products. However, under working conditions, the structure of catalysts inevitably undergoes reconstruction, hardly retaining the initial strain. Herein, we present a metal/metal oxide synthetic strategy to introduce and maintain the tensile strain in a copper/ceria heterostructure, enabled by the presence of a thin interface layer of Cu2O/CeO2. The tensile strain in the copper domain and deficient electron environment around interfacial Cu sites resulted in strengthened adsorption of carbonaceous intermediates and promoted*CO dimerization. The strain effect in the copper/ceria heterostructure leads to an improved C2+ selectivity with a maximum Faradaic efficiency of 76.4% and a half-cell power conversion efficiency of 49.1%. The fundamental insights gained from this system can facilitate the rational design of heterostructure catalysts for CO2R. | |
650 | 7 | a NATURVETENSKAPx Fysikx Den kondenserade materiens fysik0 (SwePub)103042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciencesx Condensed Matter Physics0 (SwePub)103042 hsv//eng |
653 | a copper/ceria heterostructure | |
653 | a electrocatalyst | |
653 | a electroreduction of carbon dioxide | |
653 | a synergistic effect | |
653 | a tensile strain | |
653 | a Experimentell fysik | |
653 | a Experimental Physics | |
700 | 1 | a Zhang, Haou Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123, P. R. China4 aut |
700 | 1 | a Huang, Yanu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China; Key Laboratory of Efficient Utilization of Low and Medium Grade Energy Ministry of Education, Tianjin University, Tianjin 300350, P. R. China4 aut |
700 | 1 | a Wang, Haiyuu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China4 aut |
700 | 1 | a Ozden, Adnanu Department of Mechanical and Industrial Engineering, University of Toronto, 5 King's College Road, Toronto, Ontario M5S 3G8, Canada4 aut |
700 | 1 | a Yao, Kailiu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China4 aut |
700 | 1 | a Li, Huaminu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China4 aut |
700 | 1 | a Guo, Qianyingu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China4 aut |
700 | 1 | a Liu, Yongchangu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China; State Key Lab of Hydraulic Engineering Simulation and Safety, Tianjin University, Tianjin 300350, P. R. China4 aut |
700 | 1 | a Vomiero, Albertou Luleå tekniska universitet,Materialvetenskap,Department of Molecular Sciences and Nanosystems, Ca' Foscari University of Venice 30172 Venezia Mestre, Italy4 aut0 (Swepub:ltu)albvom |
700 | 1 | a Wang, Yuhangu Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123, P. R. China4 aut |
700 | 1 | a Qian, Zhaou Key Laboratory of Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education Shandong University, Jinan 250061, P. R. China4 aut |
700 | 1 | a Li, Junu Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China4 aut |
700 | 1 | a Wang, Ziyunu School of Chemical Sciences, the University of Auckland, Auckland 1010, New Zealand4 aut |
700 | 1 | a Sun, Xuhuiu Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123, P. R. China4 aut |
700 | 1 | a Liang, Hongyanu School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China; Key Laboratory of Efficient Utilization of Low and Medium Grade Energy Ministry of Education, Tianjin University, Tianjin 300350, P. R. China4 aut |
710 | 2 | a School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P. R. China; Key Laboratory of Efficient Utilization of Low and Medium Grade Energy Ministry of Education, Tianjin University, Tianjin 300350, P. R. Chinab Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123, P. R. China4 org |
773 | 0 | t ACS Nanod : American Chemical Societyg 17:1, s. 346-354q 17:1<346-354x 1936-0851x 1936-086X |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-95280 |
856 | 4 8 | u https://doi.org/10.1021/acsnano.2c08453 |
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