Transformation of alpha-pinene using Picea abies suspension culture

Lindmark-Henriksson, Marica (author): Mittuniversitetet,Institutionen för naturvetenskap (-2008)

Isaksson, Dan (author): Mittuniversitetet,Institutionen för naturvetenskap (-2008)

Sjödin, Kristina (author): Mittuniversitetet,Institutionen för naturvetenskap (-2008)

Högberg, Hans-Erik (author): Mittuniversitetet,Institutionen för naturvetenskap (-2008)

Vanek, Tomas (author)

Valterova, Irena (author)

(creator_code:org_t)

2003-02-05
2003
English.
In: Journal of Natural Products. - : American Chemical Society (ACS). - 0163-3864 .- 1520-6025. ; 66:3, s. 337-343

Related links:: https://urn.kb.se/re...; show more...; https://doi.org/10.1...; show less...

Abstract Subject headings

alpha-Pinene, both as the pure enantiomers and as the racemate, was transformed mainly to trans-verbenol by treatment with a Picea abies suspension cell culture. These reactions were followed by a slow transformation of the verbenol to verbenone, which was not transformed further. trans-Pinocarveol, myrtenol, cis-verbenol, and alpha-terpineol were byproducts of intermediate abundance. When subjected to the action of the suspension culture, cis-verbenol was not only transformed to verbenone but also isomerized to trans-verbenol. The transformation of alpha-pinene was fast, and the products were detected within one minute. The absolute configuration of the major products corresponded to that of the starting alpha-pinene enantiomer

By the author/editor: Lindmark-Henriks ...; Isaksson, Dan; Sjödin, Kristina; Högberg, Hans-Er ...; Vanek, Tomas; Valterova, Irena

About the subject

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