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Stereoselective esterification of 2,6-dimethyl-1,7-heptanedioic acid, catalysed by Candida rugosa lipase
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- Hedenström, Erik (author)
- Mittuniversitetet,Institutionen för naturvetenskap (-2008)
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- Edlund, Helen (author)
- Mittuniversitetet,Institutionen för naturvetenskap (-2008)
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- Lund, Susan (author)
- Mittuniversitetet,Institutionen för naturvetenskap (-2008)
- (creator_code:org_t)
- 2003
- 2003
- English.
- In: Journal of Molecular Catalysis B. - 1381-1177 .- 1873-3158. ; 23:1, s. 53-59
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The immobilised Candida rugosa lipase (CRL) displayed S-preference for both stereogenic centres in this sequential esterification of 2,6-dimethyl-1,7-heptanedioic acid (1) (pure meso and meso: (+/-) mixture, 53/47) with n-butanol in cyclohexane at a(w) = 0.8. The reaction was faster when short-chain primary n-alcohols was used and very slow, or even none reactive, when a Ion-chain alcohol was used.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- organic chemistry
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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