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Analysis of trifluo...
Analysis of trifluoroacetic acid and other short-chain perfluorinated acids (C2-C4) in precipitation by liquid chromatography-tandem mass spectrometry : Comparison to patterns of long-chain perfluorinated acids (C5-C18)
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- Taniyasu, Sachi (author)
- National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki, Japan
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- Kannan, Kurunthachalam (author)
- Wadsworth Center, New York State Department of Health, Department of Environmental Health Sciences, Albany, NY, United States
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- Yeung, Leo W. Y., 1981- (author)
- Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong
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- Kwok, Karen Y. (author)
- Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong
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- Lam, Paul K. S. (author)
- Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong
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- Yamashita, Nobuyoshi (author)
- National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki, Japan
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(creator_code:org_t)
- Elsevier, 2008
- 2008
- English.
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In: Analytica Chimica Acta. - : Elsevier. - 0003-2670 .- 1873-4324. ; 619:2, s. 221-230
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A method has been developed to measure 29 perfluorinated acids (PFAs) including short-chain perfluorocarboxylates (PFCAs) such as trifluoroacetic acid (TFA; C2) and long-chain PFCAs, perfluoroalkylsulfonates, fluorotelomer acids, and two perfluorooctylsulfonamides in water matrices. The method involves solid phase extraction (SPE) using a weak anion-exchange (WAX) cartridge, an ion-exchange high-performance liquid chromatography (HPLC) column separation, and tandem mass spectrometry (MS/MS) detection. To our knowledge, this is the first HPLC-MS/MS method to determine TFA in water at sub-ng L-1 concentrations. The method is selective, simple, and robust, capable of measuring 29 PFAs in a single analysis, with overall recoveries of the target analytes ranging from 75% to 132%. The method was applied to the analysis of rainwater samples collected from two cities in Japan. TFA and several short-chain PFAs were the major compounds found in rainwater.
Subject headings
- NATURVETENSKAP -- Geovetenskap och miljövetenskap -- Miljövetenskap (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences -- Environmental Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Ion exchange; Perfluorochemicals; Perfluorooctanesulfonate; Perfluorooctanoic acid; Rain; Trifluoroacetic acid; Water
- Enviromental Science
- Miljövetenskap
- Kemi
- Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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