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Vibrational entropy-enhanced magnetocaloric effect in Mn-rich high-entropy alloys

Huang, Shuo (author)
Uppsala universitet,Materialteori,China Univ Geosci, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China.
Dong, Zhihua (author)
State Key Laboratory of Mechanical Transmissions, College of Materials Science and Engineering, Chongqing University, Chongqing, China; National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing, China,Chongqing Univ, Coll Mat Sci & Engn, State Key Lab Mech Transmiss, Chongqing 400044, Peoples R China.;Chongqing Univ, Natl Engn Res Ctr Magnesium Alloys, Chongqing 400044, Peoples R China.
Dastanpour Hosseinabadi, Esmat (author)
KTH,Isfahan Univ Technol, Dept Mat Engn, Esfahan 8415683111, Iran.;Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden.,Dept of Materials Engineering, Isfahan University of Technology, Isfahan, Iran
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Ström, Valter (author)
KTH,Materialvetenskap,Dept of Materials Science and Engineering, KTH, Stockholm,Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden.
Chai, Guocai, 1956- (author)
Linköpings universitet,Konstruktionsmaterial,Tekniska fakulteten,Sandvik Materials Technology, Sandviken,AB Sandvik Mat Technol R&D Ctr, SE-81181 Sandviken, Sweden.;Linköping Univ, Div Engn Mat, Dept Management & Engn, SE-58183 Linköping, Sweden.
Varga, Lajos Károly (author)
Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Budapest, Hungary,Wigner Res Ctr Phys, Inst Solid State Phys & Opt, H-1525 Budapest, Hungary.,Inst of Solid State Physics and Optics, Wigner Research Centre for Physics, Budapest, Hungary
Eriksson, Olle, 1960- (author)
Uppsala universitet,Örebro universitet,Institutionen för naturvetenskap och teknik,Department of Physics and Astronomy, Division of Materials Theory, Uppsala University, Uppsala, Sweden,Uppsala Univ, Div Mat Theory, Dept Phys & Astron, SE-75120 Uppsala, Sweden.;Örebro Univ, Sch Sci & Technol, SE-70182 Örebro, Sweden.,Dept of Physics and Astronomy, Materials Theory, Uppsala University and School of Science and Technology, Örebro University,Materialteori
Vitos, Levente (author)
Uppsala universitet,KTH,Materialvetenskap,Tillämpad fysik,Uppsala Univ, Div Mat Theory, Dept Phys & Astron, SE-75120 Uppsala, Sweden.;Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden.;Wigner Res Ctr Phys, Inst Solid State Phys & Opt, H-1525 Budapest, Hungary.,Dept of Physics and Astronomy, Materials Theory, Uppsala University and Dept of Materials Science and Engineering, KTH, Stockholm and Inst for Solid State Physics and Optics, Wigner Research Centre for Physics, Budapest, Hungary,Materialteori
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 (creator_code:org_t)
American Institute of Physics (AIP), 2021
2021
English.
In: Applied Physics Letters. - : American Institute of Physics (AIP). - 0003-6951 .- 1077-3118. ; 119:8
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We investigate the AlxCr0.2MnFe0.5Co0.3Ni0.5 (0.3 <= x <= 0.7) high-entropy alloys by combining experimental and theoretical techniques. X-ray diffraction and magnetization measurements indicate that Al alters the crystal structure and the entropy change upon magnetization-demagnetization while keeping the Curie temperature almost unchanged. First-principles calculations of the vibrational, magnetic, electronic, and configurational entropies show that the leading entropy change is due to the magnetic and vibrational degrees of freedom. The presence of the body-centered-cubic phase, showing a sizable elastic softening upon magnetic transition, brings about the substantial magnetocaloric effect in this family of alloys.

Subject headings

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
TEKNIK OCH TEKNOLOGIER  -- Materialteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Materials Engineering (hsv//eng)

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