Synthesis and spectroscopic characterization of Fe3+-BDC metal organic framework as material for lithium ion batteries

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Ajpi Condori, CesarioKTH,Tillämpad elektrokemi,UMSA-University (author)

Synthesis and spectroscopic characterization of Fe3+-BDC metal organic framework as material for lithium ion batteries

Article/chapterEnglish2023

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Elsevier B.V.2023
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LIBRIS-ID:oai:DiVA.org:ri-60251
https://urn.kb.se/resolve?urn=urn:nbn:se:ri:diva-60251URI
https://doi.org/10.1016/j.molstruc.2022.134127DOI
https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-318503URI

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Language:English
Summary in:English

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SwePubSwePub

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Subject category:ref swepub-contenttype
Subject category:art swepub-publicationtype

Notes

Funding details: Styrelsen för Internationellt Utvecklingssamarbete, Sida; Funding details: Kungliga Tekniska Högskolan, KTH; Funding text 1: This work is dedicated to the late Prof. Saul Cabrera. This work was supported by the SIDA (Swedish International Development Agency), KTH Royal Institute of Technology, UMSA (Universidad Mayor de San Andres) in collaboration with IIQ (Chemical Research Institute), Department of Inorganic Chemistry and Materials Science/Advanced Materials. The authors would also like to thank Alexander J. Smith for helping to improve the language of the article.; Funding text 2: Funding for this research was provided by: SIDA (Swedish International Development Agency); KTH Royal Institute of Technology, Department of Chemical Engineering, Applied Electrochemistry; UMSA Universidad Mayor de San Andres, Department of Inorganic Chemistry and Materials Science/Advanced Materials, IIQ Chemical Research Institute.
QC 20230109
This work presents synthesis and spectroscopic characterization of a new metal-organic framework (MOF). The compound Fe-BDC-DMF was synthetized by the solvothermal method and prepared via a reaction between FeCl3.6H2O and benzene-1,4-dicarboxylic acid (H2BDC) or terephthalic acid using N,N-dimethylformamide (DMF) as solvent. The powder was characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and infrared spectroscopy (IR) analysis. The electrochemical properties were investigated in a typical lithium-ion battery electrolyte by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charging and discharging. The synthetized Fe-BDC-DMF metal-organic framework (MOF) contains a mixture of three phases, identified by PXRD as: MOF-235, and MIL-53(Fe) monoclinic with C2/c and P21/c space groups. The structure of the Fe-BDC is built up from Fe3+ ions, terephalates (BDC) bridges and in-situ-generated DMF ligands. The electrochemical measurements conducted in the potential range of 0.5–3.5 V vs. Li+/Li0 show the voltage profiles of Fe-BDC and a plateau capacity of around 175 mAh/g. © 2022 The Author(s)

Subject headings and genre

TEKNIK OCH TEKNOLOGIER Maskinteknik Teknisk mekanik hsv//swe
ENGINEERING AND TECHNOLOGY Mechanical Engineering Applied Mechanics hsv//eng
NATURVETENSKAP Kemi Materialkemi hsv//swe
NATURAL SCIENCES Chemical Sciences Materials Chemistry hsv//eng
NATURVETENSKAP Kemi Oorganisk kemi hsv//swe
NATURAL SCIENCES Chemical Sciences Inorganic Chemistry hsv//eng
Lithium-ion batteries
Metal organic frameworks
Structure
Chlorine compounds
Cyclic voltammetry
Dimethylformamide
Electrochemical impedance spectroscopy
Electrolytes
Infrared spectroscopy
Ions
Iron compounds
Metal-Organic Frameworks
Metals
Organic polymers
Organic solvents
Powder metals
Scanning electron microscopy
Battery electrolyte
Dicarboxylic acid
Electrochemical-impedance spectroscopies
Fe 3+
Infrared: spectroscopy
Metalorganic frameworks (MOFs)
N-N-dimethylformamide
Solvothermal method
Spectroscopic characterization
Terephthalic acids
Kemi
Chemical Engineering

Added entries (persons, corporate bodies, meetings, titles ...)

Leiva, N.UMSA Universidad Mayor de San Andres, Bolivia (author)
Lundblad, Anders OlofRISE,Elektrifiering och pålitlighet(Swepub:ri)anders.lundblad@ri.se (author)
Lindbergh, Göran,1959-KTH,Tillämpad elektrokemi(Swepub:kth)u13qsu09 (author)
Cabrera, S.UMSA Universidad Mayor de San Andres, Bolivia (author)
KTHTillämpad elektrokemi (creator_code:org_t)

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In:Journal of Molecular Structure: Elsevier B.V.12720022-28601872-8014

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