Durability of antireflective SiO2 coatings with closed pore structure

• The use of antireflective coatings to increase the transmittance of the cover glass is a central aspect of achieving high efficiencies for solar collectors and photovoltaics alike. Considering an expected lifetime of 20–30 years for solar energy installations, the durability of the antireflective surfaces is essential. Here, a novel antireflective SiO2 coating with a hexagonally ordered closed pore structure, produced with an aerosol-based sol-gel method is benchmarked against two commercial coatings; produced with acid etching and sol-gel roll coating. The optical and mechanical properties together with contact angle characteristics were evaluated before and after various durability tests, including climate chamber tests, outdoor exposure, and abrasion. Compared to the commercial antireflective coatings with open pore structures, the novel coating performed in parity, or better, in all tests. Based on the results of humidity freeze and industrial climate chamber tests, it appears that the coating with closed pore structure has a better ability to prevent water adsorption. Additionally, the closed pore structure of the coating seems to minimize the accumulation of dirt and deposits. The abrasion and cleanability test further confirm the advantages of a closed pore structure, showcasing the coating's mechanical durability. While the coatings exhibit similar hardness and reduced elastic modulus, the closed pore coating proves to be even harder after undergoing the industrial climate chamber test, but also slightly more brittle, as indicated by the probability of crack initiation. In summary the closed pore structure is well suited for tempered and arid climates, making it a truly competitive alternative to existing antireflective coatings.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

TEKNIK OCH TEKNOLOGIER  -- Materialteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Materials Engineering (hsv//eng)

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

TEKNIK OCH TEKNOLOGIER  -- Materialteknik -- Bearbetnings-, yt- och fogningsteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Materials Engineering -- Manufacturing, Surface and Joining Technology (hsv//eng)

NATURVETENSKAP  -- Fysik -- Annan fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Other Physics Topics (hsv//eng)

TEKNIK OCH TEKNOLOGIER  -- Nanoteknik -- Nanoteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Nano-technology -- Nano-technology (hsv//eng)

Keyword

Antireflective coating

Aerosol-based deposition

Accelerated ageing

Durability

Solar collector

Solar glass

Publication and Content Type

ref (subject category)

art (subject category)