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A microporous polym...
A microporous polymer based on nonconjugated hindered biphenyls that emits blue light
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- Church, Tamara L. (author)
- Stockholm University, Sweden,Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden.
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- Eriksson, Lars (author)
- Stockholm University, Sweden,Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden.
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- Leandri, Valentina (author)
- KTH,Tillämpad fysikalisk kemi,RISE Chem Proc & Pharmaceut Dev, Forskargatan 20J, S-15136 Södertälje, Sweden,KTH Royal Institute of Technology, Sweden;
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- Gardner, James M., 1982- (author)
- KTH,Tillämpad fysikalisk kemi,KTH Royal Institute of Technology, Sweden
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- Hedin, Niklas (author)
- Stockholm University, Sweden,Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden.
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Stockholm University, Sweden Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden (creator_code:org_t)
- Springer Nature, 2024
- 2024
- English.
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In: Scientific Reports. - : Springer Nature. - 2045-2322. ; 14:1
- Related links:
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https://ri.diva-port... (primary) (Raw object)
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Microporous organic polymers that have three-dimensional connectivity stemming from monomers with tetrahedral or tetrahedron-like geometry can have high surface areas and strong fluorescence. There are however few examples of such polymers based on hindered biaryls, and their fluorescence has not been studied. Hypothesizing that the contortion in a hindered biphenyl moiety would modulate the optical properties of a polymer built from it, we synthesized a meta-enchained polyphenylene from a 2,2ʹ,6,6ʹ-tetramethylbiphenyl-based monomer, in which the two phenyl rings are nearly mutually perpendicular. The polymer was microporous with SBET = 495 m2 g−1. The polymer absorbed near-UV light and emitted blue fluorescence despite the meta-enchainment that would have been expected to break the conjugation. A related copolymer, synthesized from 2,2ʹ,6,6ʹ-tetramethylbiphenyl-based and unsubstituted biphenyl-based monomers, was microporous but not fluorescent. © The Author(s) 2024.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Keyword
- copolymer; monomer; polymer; polyphenylene; article; blue light; conjugation; controlled study; fluorescence; geometry; human; surface area; ultraviolet radiation
Publication and Content Type
- ref (subject category)
- art (subject category)
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