Combined Heterogeneous Metal/Chiral Amine: Multiple Relay Catalysis for Versatile Eco-Friendly Synthesis

Deiana, LucaStockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden (author)

Combined Heterogeneous Metal/Chiral Amine : Multiple Relay Catalysis for Versatile Eco-Friendly Synthesis

AuthorCount:9;
Herein is described a versatile and broad synergistic strategy for expansion of chemical space and the synthesis of valuable molecules (e.g. carbocycles and heterocycles), with up to three quaternary stereocenters, in a highly enantioselective fashion from simple alcohols (31examples, 95:5 to >99.5:0.5 e.r.) using integrated heterogeneous metal/chiral amine multiple relay catalysis and air/O-2 as the terminal oxidant. A novel highly 1,4-selective heterogeneous metal/amine co-catalyzed hydrogenation of enals was also added to the relay catalysis sequences.

Jiang, YanStockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden (author)
Palo-Nieto, CarlosStockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden (author)
Afewerki, SamsonMittuniversitetet,Avdelningen för naturvetenskap(Swepub:miun)samafe (author)
Incerti-Pradillos, Celia A.Mittuniversitetet,Avdelningen för naturvetenskap (author)
Verho, OscarStockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden(Swepub:su)osve3912 (author)
Tai, Cheuk-WaiStockholms universitet,Institutionen för material- och miljökemi (MMK),Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden(Swepub:su)ctai (author)
Johnston, Eric V.Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden(Swepub:su)erjo0102 (author)
Córdova, ArmandoStockholms universitet,Institutionen för organisk kemi,Mid Sweden University, Sweden,Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden(Swepub:miun)armcor (author)
Stockholms universitetInstitutionen för organisk kemi (creator_code:org_t)

In:Angewandte Chemie International Edition: Wiley53:13, s. 3447-34511433-78511521-3773

By the author/editor: Deiana, Luca; Jiang, Yan; Palo-Nieto, Carl ...; Afewerki, Samson; Incerti-Pradillo ...; Verho, Oscar; show more...; Tai, Cheuk-Wai; Johnston, Eric V ...; Córdova, Armando; show less...

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