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A Series of Highly ...
A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs
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Wang, Kecheng (author)
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Feng, Dawei (author)
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Liu, Tian-Fu (author)
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- Su, Jie (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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Yuan, Shuai (author)
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Chen, Ying-Pin (author)
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Bosch, Mathieu (author)
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- Zou, Xiaodong (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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Zhou, Hong-Cai (author)
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(creator_code:org_t)
- 2014-09-23
- 2014
- English.
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 136:40, s. 13983-13986
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A series of mesoporous metalloporphyrin Fe-MOFs, namely PCN-600(M) (M = Mn, Fe, Co, Ni, Cu), have been synthesized using the preassembled [Fe3O(OOCCH3)(6)] building block. PCN-600 exhibits a one-dimensional channel as large as 3.1 nm and the highest experimental pore volume of 1.80 cm(3) g(-1) among all the reported porphyrinic MOFs. It also shows very high stability in aqueous solutions with pH values ranging from 2-11 and is to our knowledge the only mesoporous porphyrinic MOF stable under basic aqueous conditions. PCN-600(Fe) has been demonstrated as an effective peroxidase mimic to catalyze the co-oxidation reaction.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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