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Electrocatalytic Wa...
Electrocatalytic Water Oxidation by a Dinuclear Copper Complex in a Neutral Aqueous Solution
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Su, Xiao-Jun (author)
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Gao, Meng (author)
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Jiao, Lei (author)
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Liao, Rong-Zhen (author)
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- Siegbahn, Per E. M. (author)
- Stockholms universitet,Institutionen för organisk kemi
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Cheng, Jin-Pei (author)
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Zhang, Ming-Tian (author)
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(creator_code:org_t)
- 2015-02-10
- 2015
- English.
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In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 54:16, s. 4909-4914
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Electrocatalytic water oxidation using the oxidatively robust 2,7-[bis(2-pyridylmethyl)aminomethyl]-1,8-naphthyridine ligand (BPMAN)-based dinuclear copper(II) complex, [Cu-2(BPMAN)(-OH)](3+), has been investigated. This catalyst exhibits high reactivity and stability towards water oxidation in neutral aqueous solutions. DFT calculations suggest that the OO bond formation takes place by an intramolecular direct coupling mechanism rather than by a nucleophilic attack of water on the high-oxidation-state (CuO)-O-IV moiety.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- copper
- homogeneous catalysis
- OO coupling
- superoxide complexes
- water oxidation
Publication and Content Type
- ref (subject category)
- art (subject category)
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