onr:"swepub:oai:DiVA.org:su-117724"
Search: onr:"swepub:oai:DiVA.org:su-117724" > Mild Deoxygenation ...
- 1 of 1
- Previous record
- Next record
- To hitlist
Mild Deoxygenation of Aromatic Ketones and Aldehydes over Pd/C Using Polymethylhydrosiloxane as the Reducing Agent
-
- Volkov, Alexey (author)
- Stockholms universitet,Institutionen för organisk kemi
-
- Gustafson, Karl P. J. (author)
- Stockholms universitet,Institutionen för organisk kemi
-
- Tai, Cheuk-Wai (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
- show more...
- show less...
- (creator_code:org_t)
- 2015-02-26
- 2015
- English.
- In: Angewandte Chemie International Edition. - : Wiley-VCH Verlagsgesellschaft. - 1433-7851 .- 1521-3773. ; 54:17, s. 5122-5126
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- Herein, a practical and mild method for the deoxygenation of a wide range of benzylic aldehydes and ketones is described, which utilizes heterogeneous Pd/C as the catalyst together with the green hydride source, polymethylhydrosiloxane. The developed catalytic protocol is scalable and robust, as exemplified by the deoxygenation of ethyl vanillin, which was performed on a 30 mmol scale in an open-to-air setup using only 0.085 mol% Pd/C catalyst to furnish the corresponding deoxygenated product in 93% yield within 3 hours at room temperature. Furthermore, the Pd/C catalyst was shown to be recyclable up to 6 times without any observable decrease in efficiency and it exhibited low metal leaching under the reaction conditions.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- deoxygenation
- heterogeneous catalysis
- ketones
- palladium
- silanes
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Angewandte Chemie International Edition (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Volkov, Alexey
- Gustafson, Karl ...
- Tai, Cheuk-Wai
- Verho, Oscar
- Bäckvall, Jan-E.
- Adolfsson, Hans
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- Articles in the publication
- Angewandte Chemi ...
- By the university
- Stockholm University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
