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PKU-3 :
PKU-3 : An HCI-Inclusive Aluminoborate for Strecker Reaction Solved by Combining RED and PXRD
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- Chen, Hong (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),China University of Geosciences, China
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Ju, Jing (author)
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- Meng, Qingpeng (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Su, Jie (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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Lin, Cong (author)
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Zhou, Zhengyang (author)
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Li, Guobao (author)
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Wang, Weilu (author)
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Gao, Wenliang (author)
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Zeng, Chunmei (author)
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Tang, Chiu (author)
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Lin, Jianhua (author)
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Yang, Tao (author)
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- Sun, Junliang (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Peking University, China
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(creator_code:org_t)
- 2015-05-29
- 2015
- English.
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 137:22, s. 7047-7050
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A novel microporous aluminoborate, denoted as PKU-3, was prepared by the boric acid flux method. The structure of PKU-3 was determined by combining the rotation electron diffraction and synchrotron powder X-ray diffraction data with well resolved ordered Cl- ions in the channel. Composition and crystal structure analysis showed that there are both proton and chlorine ions in the channels. Part of these protons and chlorine ions can be washed away by basic solutions to activate the open pores. The washed PKU-3 can be used as an efficient catalyst in the Strecker reaction with yields higher than 90%.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Chen, Hong
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Ju, Jing
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Meng, Qingpeng
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Su, Jie
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Lin, Cong
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Zhou, Zhengyang
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show more...
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Li, Guobao
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Wang, Weilu
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Gao, Wenliang
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Zeng, Chunmei
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Tang, Chiu
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Lin, Jianhua
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Yang, Tao
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Sun, Junliang
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
- Articles in the publication
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Journal of the A ...
- By the university
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Stockholm University