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Synthesis of Adjace...
Synthesis of Adjacent Quaternary Stereocenters by Catalytic Asymmetric Allylboration
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- Alam, Rauful (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Vollgraff, Tobias (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Eriksson, Lars (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Szabó, Kálmán J. (author)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- 2015-08-31
- 2015
- English.
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 137:35, s. 11262-11265
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https://doi.org/10.1...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- Allylboration of ketones with gamma-disubstituted allylboronic acids is performed in the presence of chiral BINOL derivatives. The reaction is suitable for single-step creation of adjacent quaternary stereocenters with high selectivity. We show that, with an appropriate choice of the chiral catalyst and the stereoisomeric prenyl substrate, full control of the stereo- and enantioselectivity is possible in the reaction.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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