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A ruthenium water o...
A ruthenium water oxidation catalyst based on a carboxamide ligand
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- Rabten, Wangchuk (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Åkermark, Torbjörn (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Kärkäs, Markus D. (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Chen, Hong (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),China University of Geosciences, China
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- Sun, Junliang (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Peking University, China
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- Andersson, Pher G. (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Åkermark, Björn (author)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- 2016
- 2016
- English.
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In: Dalton Transactions. - : Royal Society of Chemistry (RSC). - 1477-9226 .- 1477-9234. ; 45:8, s. 3272-3276
- Related links:
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https://doi.org/10.1...
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https://pubs.rsc.org...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- Herein is presented a single-site Ru complex bearing a carboxamide-based ligand that efficiently manages to carry out the fourelectron oxidation of H2O. The incorporation of the negatively charged ligand framework significantly lowered the redox potentials of the Ru complex, allowing H2O oxidation to be driven by the mild oxidant [Ru(bpy)(3)](3+). This work highlights that the inclusion of amide moieties into metal complexes thus offers access to highly active H2O oxidation catalysts.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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