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Palladium-Catalyzed Oxidative Synthesis of a-Acetoxylated Enones from Alkynes
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- Jiang, Tuo (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Quan, Xu (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Zhu, Can (author)
- Stockholms universitet,Institutionen för organisk kemi
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- (creator_code:org_t)
- 2016-04-06
- 2016
- English.
- In: Angewandte Chemie International Edition. - : Wiley-VCH Verlagsgesellschaft. - 1433-7851 .- 1521-3773. ; 55:19, s. 5824-5828
- Journal article (peer-reviewed)
Abstract
Subject headings
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- We report a palladium-catalyzed oxidative functionalization of alkynes to generate -acetoxylated enones in one step. A range of functional groups are well-tolerated in this reaction. Mechanistic studies, including the use of O-18-labeled DMSO, revealed that the ketone oxygen atom in the product originates from DMSO.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- alkynes
- enones
- oxidation
- palladium
- sulfoxides
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Bäckvall, Jan-E.
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