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Diglycidylether of ...
Diglycidylether of iso-eugenol : a suitable lignin-derived synthon for epoxy thermoset applications
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- Francois, Camille (author)
- ICMUB Institute;Department of Electrochemistry;Molecular Materials and Devices;UMR-CNRS 6302;University of Bourgogne Franche-Comté
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- Pourchet, Sylvie (author)
- ICMUB Institute;Department of Electrochemistry;Molecular Materials and Devices;UMR-CNRS 6302;University of Bourgogne Franche-Comté
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- Boni, Gilles (author)
- ICMUB Institute;Department of Electrochemistry;Molecular Materials and Devices;UMR-CNRS 6302;University of Bourgogne Franche-Comté
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- Fontaine, Stephane (author)
- DRIVE Laboratory;Institut Supérieur de l'Automobile et des Transports;F-58027 Nevers;France
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- Gaillard, Yves (author)
- FEMTO Institute;Applied Mechanics Department;UMR CNRS 6174;University of Franche-Comté;F-25000 Besançon
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- Placet, Vincent (author)
- FEMTO Institute;Applied Mechanics Department;UMR CNRS 6174;University of Franche-Comté;F-25000 Besançon
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- Galkin, Maxim V. (author)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry;Arrhenius Laboratory;Stockholm University;S-106 91 Stockholm;Sweden
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- Orebom, Alexander (author)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry;Arrhenius Laboratory;Stockholm University;S-106 91 Stockholm;Sweden
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- Samec, Joseph (author)
- Stockholms universitet,Institutionen för organisk kemi,Department of Organic Chemistry;Arrhenius Laboratory;Stockholm University;S-106 91 Stockholm;Sweden
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- Plasseraud, Laurent (author)
- ICMUB Institute;Department of Electrochemistry;Molecular Materials and Devices;UMR-CNRS 6302;University of Bourgogne Franche-Comté
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(creator_code:org_t)
- 2016
- 2016
- English.
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In: RSC Advances. - : Royal Society of Chemistry. - 2046-2069. ; 6:73, s. 68732-68738
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A novel lignin-based synthon, diglycidylether of iso-eugenol (DGE-isoEu) is used as a prepolymer for the preparation of thermosetting resins. DGE-isoEu is synthesized in a two-step procedure with a satisfactory yield from bio-based iso-eugenol (isoEu, 2-methoxy-4-(1-propenyl)phenol) catalytically fragmented from lignin in an organosolv process. DGE-isoEu was fully characterized by NMR, MS and FTIR. Curing of the DGE-isoEu monomer has then been investigated in the presence of several carboxylic acid derivatives hardeners. The thermal and mechanical properties of each material were recorded showing, in particular, a high T-g and instantaneous modulus values in the range of 78-120 degrees C and 4.6-5.5 GPa, respectively. The lignin derived new materials give very attractive thermo-mechanical properties comparable to that of common BPA-containing epoxy resins.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Francois, Camill ...
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Pourchet, Sylvie
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Boni, Gilles
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Fontaine, Stepha ...
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Gaillard, Yves
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Placet, Vincent
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show more...
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Galkin, Maxim V.
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Orebom, Alexande ...
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Samec, Joseph
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Plasseraud, Laur ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Polymer Chemistr ...
- Articles in the publication
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RSC Advances
- By the university
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Stockholm University
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Uppsala University