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Efficient DBU accelerated synthesis of F-18-labelled trifluoroacetamides
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- Bermejo Gómez, Antonio (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Cortés González, Miguel A. (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Lübcke, Marvin (author)
- Stockholms universitet,Institutionen för organisk kemi,Karolinska Institutet, Sweden
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- Johansson, Magnus J. (author)
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- (creator_code:org_t)
- 2016
- 2016
- English.
- In: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1359-7345 .- 1364-548X. ; 52:97, s. 13963-13966
- Journal article (peer-reviewed)
Abstract
Subject headings
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- Nucleophilic F-18-fluorination of bromodifluoromethyl derivatives was performed using [F-18] Bu4NF in the presence of DBU(1,8-diazabicyclo[5.4.0]undec-7-ene). This novel procedure provided a diverse set of [F-18] trifluoroacetamides in good to excellent radiochemical conversions. A mechanism where DBU acts as organomediator in this transformation is proposed.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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