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Rhodium-catalyzed a...
Rhodium-catalyzed asymmetric transfer hydrogenation of alkyl and aryl ketones in aqueous media
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- Ahlford, Katrin (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Lind, Jesper (author)
- Stockholms universitet,Institutionen för biokemi och biofysik
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- Mäler, Lena (author)
- Stockholms universitet,Institutionen för biokemi och biofysik
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- Adolfsson, Hans (author)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2008
- 2008
- English.
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In: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270. ; 10:8, s. 832-835
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A novel lipophilic rhodium catalyst was evaluated in the enantioselective transfer hydrogenation of ketones in water using sodium formate as the hydride donor, and in the presence of sodium docecylsulfonate. Alkyl alkyl ketones were reduced in good yields and in moderate to good enantioselectivities, and the reduction of aryl alkyl ketones proceeded with excellent enantioselectivity (up to 97% ee).
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Organic chemistry
- Organisk kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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