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Low-Energy Collisio...
Low-Energy Collisions of Protonated Enantiopure Amino Acids with Chiral Target Gases
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- Kulyk, Kostiantyn (author)
- Stockholms universitet,Fysikum,SCA R&D Centre, Sweden
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- Rebrov, Oleksii (author)
- Stockholms universitet,Fysikum
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Ryding, M. (author)
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- Thomas, Richard D. (author)
- Stockholms universitet,Fysikum
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Uggerud, E. (author)
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- Larsson, Mats (author)
- Stockholms universitet,Fysikum
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(creator_code:org_t)
- 2017-09-21
- 2017
- English.
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In: Journal of the American Society for Mass Spectrometry. - : American Chemical Society (ACS). - 1044-0305 .- 1879-1123. ; 28:12, s. 2686-2691
- Related links:
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https://doi.org/10.1...
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https://europepmc.or...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- Here we report on the gas-phase interactions between protonated enantiopure amino acids (l- and d-enantiomers of Met, Phe, and Trp) and chiral target gases [(R)- and (S)-2-butanol, and (S)-1-phenylethanol] in 0.1-10.0 eV low-energy collisions. Two major processes are seen to occur over this collision energy regime, collision-induced dissociation and ion-molecule complex formation. Both processes were found to be independent of the stereo-chemical composition of the interacting ions and targets. These data shed light on the currently debated mechanisms of gas-phase chiral selectivity by demonstrating the inapplicability of the three-point model to these interactions, at least under single collision conditions.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Collision induced dissociation
- Chiral target gases
- Chirality
- Low-energy collisions
- Enantiopure amino acids
- Gas-phase complexes
- fysik
- Physics
Publication and Content Type
- ref (subject category)
- art (subject category)
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