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Intermolecular Pumm...
Intermolecular Pummerer Coupling with Carbon Nucleophiles in Non-Electrophilic Media
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- Colas, Kilian (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Martín-Montero, Raúl (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Mendoza, Abraham (author)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- 2017-11-15
- 2017
- English.
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In: Angewandte Chemie International Edition. - : Wiley-VCH Verlagsgesellschaft. - 1433-7851 .- 1521-3773. ; 56:50, s. 16042-16046
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Abstract
Subject headings
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- A new Pummerer-type C-C coupling protocol is introduced based on turbo-organomagnesium amides, which unlike traditional Pummerer reactions, does not require strong electrophilic activators, engages a broad range of C(sp(3))-, C(sp(2))-, and C(sp)-nucleophiles, and seamlessly integrates with C-H and C-X magnesiation. Given the central character of sulfur compounds in organic chemistry, this protocol allows access to unrelated carbonyls, olefins, organometallics, halides, and boronic esters through a single strategy.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- C-C coupling
- magnesium
- main group elements
- Pummerer reaction
- sulfur
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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