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Intermolecular Pumm...
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Colas, KilianStockholms universitet,Institutionen för organisk kemi
(author)
Intermolecular Pummerer Coupling with Carbon Nucleophiles in Non-Electrophilic Media
- Article/chapterEnglish2017
Publisher, publication year, extent ...
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2017-11-15
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Wiley-VCH Verlagsgesellschaft,2017
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electronicrdacarrier
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LIBRIS-ID:oai:DiVA.org:su-150977
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https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-150977URI
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https://doi.org/10.1002/anie.201709715DOI
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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A new Pummerer-type C-C coupling protocol is introduced based on turbo-organomagnesium amides, which unlike traditional Pummerer reactions, does not require strong electrophilic activators, engages a broad range of C(sp(3))-, C(sp(2))-, and C(sp)-nucleophiles, and seamlessly integrates with C-H and C-X magnesiation. Given the central character of sulfur compounds in organic chemistry, this protocol allows access to unrelated carbonyls, olefins, organometallics, halides, and boronic esters through a single strategy.
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Martín-Montero, RaúlStockholms universitet,Institutionen för organisk kemi
(author)
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Mendoza, AbrahamStockholms universitet,Institutionen för organisk kemi(Swepub:su)amend
(author)
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Stockholms universitetInstitutionen för organisk kemi
(creator_code:org_t)
Related titles
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In:Angewandte Chemie International Edition: Wiley-VCH Verlagsgesellschaft56:50, s. 16042-160461433-78511521-3773
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