Sökning: onr:"swepub:oai:DiVA.org:su-166655" > Vacancy-ordered ytt...
Fältnamn | Indikatorer | Metadata |
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000 | 02862naa a2200433 4500 | |
001 | oai:DiVA.org:su-166655 | |
003 | SwePub | |
008 | 190307s2019 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-1666552 URI |
024 | 7 | a https://doi.org/10.1016/j.jeurceramsoc.2018.11.0312 DOI |
040 | a (SwePub)su | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Song, Lu4 aut |
245 | 1 0 | a Vacancy-ordered yttria stabilized zirconia as a low-temperature electronic conductor achieved by laser melting |
264 | 1 | b Elsevier BV,c 2019 |
338 | a print2 rdacarrier | |
520 | a Laser melting is known to be capable in initiating thorough evolution in microstructure and bringing novel functional performance in metals. But realization of this potential in ceramics only reaches a preliminary stage that needs further investigation. Here we demonstrate zirconia, traditionally an insulative ceramic at low temperature, could be transformed into an electronic conductor with the conductivity on order of 10(-3) S.cm(-1) at room temperature by a simple laser melting process without inducing metallic phases. Transmission electron microscopy and ab-initio simulation show that oversaturated oxygen vacancies, together with their ordered metastable distribution along < 001 >, are introduced during this non-equilibrium process, and result in a clear defect level significantly narrowing bandgap to less than 1 eV, leading to the considerable electronic conductivity. These results identify a strategy of utilizing this non-equilibrium method in oxide ceramics to realize some unconventional performances determined by metastable structure thoroughly altered down to atomic level. | |
650 | 7 | a NATURVETENSKAPx Kemi0 (SwePub)1042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciences0 (SwePub)1042 hsv//eng |
653 | a Laser melting | |
653 | a Yttria stabilized zirconia (YSZ) | |
653 | a Electronic conductivity | |
653 | a Defect ordering | |
653 | a Metastable | |
700 | 1 | a Zhang, Qinghua4 aut |
700 | 1 | a Ma, Jing4 aut |
700 | 1 | a Chen, Chonglin4 aut |
700 | 1 | a Xu, Ben4 aut |
700 | 1 | a Zhu, Mingke4 aut |
700 | 1 | a Xu, Xing4 aut |
700 | 1 | a Nan, Cewen4 aut |
700 | 1 | a Shen, Zhijianu Stockholms universitet,Institutionen för material- och miljökemi (MMK),School of Materials Science and Engineering, China4 aut0 (Swepub:su)shen |
710 | 2 | a Stockholms universitetb Institutionen för material- och miljökemi (MMK)4 org |
773 | 0 | t Journal of the European Ceramic Societyd : Elsevier BVg 39:4, s. 1374-1380q 39:4<1374-1380x 0955-2219x 1873-619X |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-166655 |
856 | 4 8 | u https://doi.org/10.1016/j.jeurceramsoc.2018.11.031 |
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