Divergent Chemistry Paths for 3D and 1D Metallo-Covalent Organic Frameworks (COFs)

The marriage of dynamic covalent chemistry (DCC) and coordination chemistry is a powerful tool for assembling complex architectures from simple building units. Recently, the synthesis of woven covalent organic frameworks (COFs) with topologically fascinating structures has been achieved using this approach. However, the scope is highly limited and there is a need to discover new pathways that can assemble covalently linked organic threads into crystalline frameworks. Herein, we have identified branching pathways leading to the assembly of three-dimensional (3D) woven COFs or one-dimensional (1D) metallo-COFs (mCOFs), where the mechanism is underpinned by the absence or presence of ligand exchange.

Luo, YiStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)yluo (author)
See, Pei Zhen (author)
Li, Xing (author)
Chen, Zhongxin (author)
Zhou, Yi (author)
Zhao, Xiaoxu (author)
Leng, Kai (author)
Park, In-Hyeok (author)
Li, Runlai (author)
Liu, Cuibo (author)
Chen, Fangzheng (author)
Xi, Shibo (author)
Sun, JunliangStockholms universitet,Institutionen för material- och miljökemi (MMK),Peking University, China(Swepub:su)jsun (author)
Loh, Kian Ping (author)
Stockholms universitetInstitutionen för material- och miljökemi (MMK) (creator_code:org_t)

In:Angewandte Chemie International Edition: Wiley59:28, s. 11527-115321433-78511521-3773

By the author/editor: Xu, Hai-Sen; Luo, Yi; See, Pei Zhen; Li, Xing; Chen, Zhongxin; Zhou, Yi; show more...; Zhao, Xiaoxu; Leng, Kai; Park, In-Hyeok; Li, Runlai; Liu, Cuibo; Chen, Fangzheng; Xi, Shibo; Sun, Junliang; Loh, Kian Ping; show less...

About the subject

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.