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  • Zheng, ZhiyaoStockholms universitet,Institutionen för organisk kemi,Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. (author)

Efficient Heterogeneous Copper-Catalyzed Alder-Ene Reaction of Allenynamides to Pyrrolines

  • Article/chapterEnglish2022

Publisher, publication year, extent ...

  • 2022-01-18
  • American Chemical Society (ACS),2022
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:su-202043
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-202043URI
  • https://doi.org/10.1021/acscatal.1c05147DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:miun:diva-44181URI

Supplementary language notes

  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • Herein, we describe an efficient nanocopper-catalyzed Alder-ene reaction of allenynamides. The copper nanoparticles were immobilized on amino-functionalized microcrystalline cellulose. A solvent-controlled chemoselectivity of the reaction was observed, leading to the chemodivergent synthesis of pyrrolines (2,5-dihydropyrroles) and pyrroles. The heterogeneous copper catalyst exhibits high efficiency and good recyclability in the Alder-ene reaction, constituting a highly attractive catalytic system from an economical and environmental point of view. 

Subject headings and genre

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  • Deiana, LucaMittuniversitetet,Institutionen för naturvetenskap(Swepub:miun)lucdei (author)
  • Posevins, DanielsStockholms universitet,Institutionen för organisk kemi,Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden.(Swepub:su)dpose (author)
  • Abbaszad Rafi, AbdolrahimMittuniversitetet,Institutionen för naturvetenskap(Swepub:miun)abdabb (author)
  • Zhang, KaihengMittuniversitetet,Institutionen för naturvetenskap(Swepub:miun)kaizha (author)
  • Johansson, Magnus J.AstraZeneca R&D, Innovat Med Cardiovasc & Metab Disorders, Med Chem, SE-43183 Mölndal, Sweden. (author)
  • Tai, Cheuk-WaiStockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden.(Swepub:su)ctai (author)
  • Cordova, Armando,1970-Mittuniversitetet,Institutionen för naturvetenskap(Swepub:miun)armcor (author)
  • Bäckvall, Jan-E.Mittuniversitetet,Stockholms universitet,Institutionen för organisk kemi,Mid Sweden University, Sweden,Institutionen för naturvetenskap,Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden.(Swepub:miun)janbac (author)
  • Stockholms universitetInstitutionen för organisk kemi (creator_code:org_t)

Related titles

  • In:ACS Catalysis: American Chemical Society (ACS)12:3, s. 1791-17962155-5435

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