A New Family of Renewable Thermosets: Kraft Lignin Poly-adipates

A New Family of Renewable Thermosets : Kraft Lignin Poly-adipates

Di Francesco, Davide, 1989- (author): Stockholms universitet,Institutionen för organisk kemi

Rigo, Davide (author)

Baddigam, Kiran Reddy (author): Stockholms universitet,Institutionen för organisk kemi

Mathew, Aji P., 1971- (author): Stockholms universitet,Institutionen för material- och miljökemi (MMK)

Hedin, Niklas (author): Stockholms universitet,Institutionen för material- och miljökemi (MMK)

Selva, Maurizio (author)

Samec, Joseph S. M. (author): Stockholms universitet,Institutionen för organisk kemi,Chulalongkorn University, Thailand

(creator_code:org_t)

Related links:: https://doi.org/10.1...; show more...; https://urn.kb.se/re...; https://doi.org/10.1...; show less...

Abstract Subject headings

Thermosetting polymeric materials have advantageous properties and are therefore used in numerous applications. In this study, it was hypothesized and ultimately shown that thermosets could be derived from comparably sustainable sub-components. A two-step procedure to produce a thermoset comprising of Kraft lignin (KL) and the cross-linker adipic acid (AdA) was developed. The cross-linking was activated by means of an acetylating agent comprising isopropenyl acetate (IPA) to form a cross-linking mixture (CLM). The cross-linking was confirmed by FTIR and solid-state NMR spectroscopy, and the esterification reactions were further studied using model compounds. When the KL lignin was mixed with the CLM, partial esterification occurred to yield a homogeneous viscous liquid that could easily be poured into a mold, as the first step in the procedure. Without any additions, the mold was heated and the material transformed into a thermoset by reaction of the two carboxylic acid-derivatives of AdA and KL in the second step.

By the author/editor: Di Francesco, Da ...; Rigo, Davide; Baddigam, Kiran ...; Mathew, Aji P., ...; Hedin, Niklas; Selva, Maurizio; show more...; Samec, Joseph S. ...; show less...

About the subject

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