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An unusual zig-zag ...
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Bilgic, Mehmet B.
(author)
An unusual zig-zag 2D copper(i) coordination polymer as an outstanding catalyst for azide–alkyne “click” chemistry at room temperature
- Article/chapterEnglish2022
Publisher, publication year, extent ...
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2022
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Royal Society of Chemistry (RSC),2022
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Numbers
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LIBRIS-ID:oai:DiVA.org:su-212580
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https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-212580URI
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https://doi.org/10.1039/d2dt03006cDOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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A straightforward method for the synthesis of a two-dimensional (2D) new copper(I) coordination polymer, namely Cu(bzpdc), containing the ligand benzophenone 4,4′-dicarboxylate, and its effective use as catalyst for the azide–alkyne click chemistry at room temperature is reported. Zig-zag formation caused by cuprophilic interactions resulted in an unprecedented crystal structure with a very high copper content (45.5% by weight). The catalyst was stable up until 300 °C and tolerant to various solvents, including water. Cu(bzpdc) showed excellent catalytic activity for click reactions of several organic azides and alkynes having different functional groups at room temperature and is comparable to its homogenous analogues. The recyclability of Cu(bzpdc) was also tested and proven to be effective.
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Kocaarslan, Azra
(author)
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Kaya, KeremStockholms universitet,Institutionen för material- och miljökemi (MMK),Istanbul Technical University, Turkey(Swepub:su)Kerem
(author)
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Atsay, Armagan
(author)
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Svensson Grape, ErikStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)ersv6431
(author)
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Chen, JianhongStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)jich2514
(author)
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Yagci, Yusuf
(author)
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Stockholms universitetInstitutionen för material- och miljökemi (MMK)
(creator_code:org_t)
Related titles
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In:Dalton Transactions: Royal Society of Chemistry (RSC)51:46, s. 17543-175461477-92261477-9234
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