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Modular Synthesis o...
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Chowdhury, Rajdip,1993-Stockholms universitet,Institutionen för organisk kemi
(author)
Modular Synthesis of (Borylmethyl)silanes through Orthogonal Functionalization of a Carbon Atom
- Article/chapterEnglish2023
Publisher, publication year, extent ...
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2023-03-10
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American Chemical Society (ACS),2023
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:su-216444
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https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-216444URI
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https://doi.org/10.1021/acs.orglett.3c00474DOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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(Borylmethyl)trimethylsilanes are important building blocks in organic synthesis displaying a unique reactivity. Yet, the synthesis of more advanced derivatives is limited by the advanced silicon intermediates required for their preparation. Herein, a one-pot synthesis of (borylmethyl)silanes is developed, sourced on available alkyl-, aryl-, alkoxy-, aryloxy-, and silyl-hydrosilane materials. The privileged reactivity of N-hydroxyphthalimidyl diazoacetate (NHPI-DA) in Si–H insertion and α-silyl redox-active esters in different decarboxylative borylation reactions are scrutinized.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Elek, Gábor ZoltánStockholms universitet,Institutionen för organisk kemi,Tallinn University of Technology, Estonia(Swepub:su)gael2454
(author)
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Meana-Baamonde, BeatrizStockholms universitet,Institutionen för organisk kemi,University of Valencia, Spain(Swepub:su)beme7015
(author)
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Mendoza, AbrahamStockholms universitet,Institutionen för organisk kemi,University of Valencia, Spain(Swepub:su)amend
(author)
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Stockholms universitetInstitutionen för organisk kemi
(creator_code:org_t)
Related titles
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In:Organic Letters: American Chemical Society (ACS)25:11, s. 1935-19401523-70601523-7052
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