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Modular Synthesis o...
Modular Synthesis of (Borylmethyl)silanes through Orthogonal Functionalization of a Carbon Atom
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- Chowdhury, Rajdip, 1993- (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Elek, Gábor Zoltán (author)
- Stockholms universitet,Institutionen för organisk kemi,Tallinn University of Technology, Estonia
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- Meana-Baamonde, Beatriz (author)
- Stockholms universitet,Institutionen för organisk kemi,University of Valencia, Spain
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- Mendoza, Abraham (author)
- Stockholms universitet,Institutionen för organisk kemi,University of Valencia, Spain
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(creator_code:org_t)
- 2023-03-10
- 2023
- English.
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In: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 25:11, s. 1935-1940
- Related links:
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- (Borylmethyl)trimethylsilanes are important building blocks in organic synthesis displaying a unique reactivity. Yet, the synthesis of more advanced derivatives is limited by the advanced silicon intermediates required for their preparation. Herein, a one-pot synthesis of (borylmethyl)silanes is developed, sourced on available alkyl-, aryl-, alkoxy-, aryloxy-, and silyl-hydrosilane materials. The privileged reactivity of N-hydroxyphthalimidyl diazoacetate (NHPI-DA) in Si–H insertion and α-silyl redox-active esters in different decarboxylative borylation reactions are scrutinized.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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