Search: onr:"swepub:oai:DiVA.org:su-229270" >
The mutual neutrali...
The mutual neutralization of hydronium and hydroxide
-
Bogot, Alon (author)
-
- Poline, Mathias, 1993- (author)
- Stockholms universitet,Fysikum
-
- Ji, MingChao, 1986- (author)
- Stockholms universitet,Fysikum
-
show more...
-
- Dochain, Arnaud, 1989- (author)
- Stockholms universitet,Fysikum
-
- Simonsson, Ansgar, 1961- (author)
- Stockholms universitet,Fysikum
-
- Rosén, Stefan, 1967- (author)
- Stockholms universitet,Fysikum
-
- Zettergren, Henning, 1975- (author)
- Stockholms universitet,Fysikum
-
- Schmidt, Henning T., 1966- (author)
- Stockholms universitet,Fysikum
-
- Thomas, Richard D., 1972- (author)
- Stockholms universitet,Fysikum
-
Strasser, Daniel (author)
-
show less...
-
(creator_code:org_t)
- 2024
- 2024
- English.
-
In: Science. - 0036-8075 .- 1095-9203. ; 383:6680, s. 285-289
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- Mutual neutralization of hydronium (H3O+) and hydroxide (OH−) ions is a very fundamental chemical reaction. Yet, there is only limited experimental evidence about the underlying reaction mechanisms. Here, we report three-dimensional imaging of coincident neutral products of mutual-neutralization reactions at low collision energies of cold and isolated ions in the cryogenic double electrostatic ion-beam storage ring (DESIREE). We identified predominant H2O + OH + H and 2OH + H2 product channels and attributed them to an electron-transfer mechanism, whereas a minor contribution of H2O + H2O with high internal excitation was attributed to proton transfer. The reported mechanism-resolved internal product excitation, as well as collision-energy and initial ion-temperature dependence, provide a benchmark for modeling charge-transfer mechanisms.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
-
Science
(Search for host publication in LIBRIS)
To the university's database
- By the author/editor
-
Bogot, Alon
-
Poline, Mathias, ...
-
Ji, MingChao, 19 ...
-
Dochain, Arnaud, ...
-
Simonsson, Ansga ...
-
Rosén, Stefan, 1 ...
-
show more...
-
Zettergren, Henn ...
-
Schmidt, Henning ...
-
Thomas, Richard ...
-
Strasser, Daniel
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Physical Chemist ...
- Articles in the publication
-
Science
- By the university
-
Stockholm University