onr:"swepub:oai:DiVA.org:su-42169"
Search: onr:"swepub:oai:DiVA.org:su-42169" > Rhodium-catalysed c...
- 1 of 1
- Previous record
- Next record
- To hitlist
Rhodium-catalysed coupling of allylic, homoallylic, and bishomoallylic alcohols with aldehydes and N-tosylimines : insights into the mechanism
-
- Ahlsten, Nanna, 1982- (author)
- Stockholms universitet,Institutionen för organisk kemi
-
- Martín-Matute, Belén (author)
- Stockholms universitet,Institutionen för organisk kemi
- (creator_code:org_t)
- 2009-10-21
- 2009
- English.
- In: Advanced Synthesis and Catalysis. - : Wiley. - 1615-4150 .- 1615-4169. ; 351:16, s. 2657-2666
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- The isomerisation of alkenols followed by reaction with aldehydes or N-tosylimines catalysed by rhodium complexes has been studied. The catalytically active rhodium complex is formed in situ from commercially available (cyclooctadiene)rhodium(l) chloride dimer [Rh(COD)Cl](2). The tandem process affords aldol and Mannich-type products in excellent yields. The key to the success of the coupling reaction is the activation of the catalysts by reaction with postassium tert-butoxide (t-BuOK), which promotes a catalytic cycle via alkoxides rather than rhodium hydrides. This mechanism minimises the formation of unwanted by-products. The mechanism has been studied by (1)H NMR spectroscopy and deuterium labelling experiments.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- aldehydes
- allylic alcohols
- isomerization
- rhodium
- N-tosylmines
- Organic chemistry
- Organisk kemi
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Advanced Synthesis and Catalysis (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Ahlsten, Nanna, ...
- Martín-Matute, B ...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Organic Chemistr ...
- Articles in the publication
- Advanced Synthes ...
- By the university
- Stockholm University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
