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Core-valence double...
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Andersson, Egil,1981-Uppsala universitet,Mjukröntgenfysik
(author)
Core-valence double photoionization of the CS2 molecule
- Article/chapterEnglish2010
Publisher, publication year, extent ...
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AIP Publishing,2010
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:su-50299
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https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-50299URI
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https://doi.org/10.1063/1.3469812DOI
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-26693URI
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-122570URI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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authorCount :10
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QC 20101130
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Double photoionization spectra of the CS2 molecule have been recorded using the TOF-PEPECO technique in combination with synchrotron radiation at the photon energies h nu=220, 230, 240, 243, and 362.7 eV. The spectra were recorded in the S 2p and C 1s inner-shell ionization regions and reflect dicationic states formed out of one inner-shell vacancy and one vacancy in the valence region. MCSCF calculations were performed to model the energies of the dicationic states. The spectra associated with a S 2p vacancy are well structured and have been interpreted in some detail by comparison to conventional S 2p and valence photoelectron spectra. The lowest inner-shell-valence dicationic state is observed at the vertical double ionization energy 188.45 eV and is associated with a (2p(3/2))(-1)(2 pi(g))(-1) double vacancy. The spectrum connected to the C 1s vacancy shows a distinct line at 310.8 eV, accompanied by additional broad features at higher double ionization energies. This line is associated with a (C 1s)(-1)(2 pi(g))(-1) double vacancy. (C-) 2010 American Institute of Physics. [doi: 10.1063/1.3469812]
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Niskanen, JohannesKTH,Teoretisk kemi(Swepub:kth)u1ylv8dn
(author)
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Hedin, LageUppsala universitet,Mjukröntgenfysik(Swepub:uu)lahed765
(author)
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Eland, John H. D.Uppsala universitet,Mjukröntgenfysik(Swepub:uu)johel911
(author)
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Linusson, PerStockholms universitet,Fysikum(Swepub:su)peli6361
(author)
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Karlsson, LeifUppsala universitet,Mjukröntgenfysik(Swepub:uu)leifkarl
(author)
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Rubensson, Jan-ErikUppsala universitet,Mjukröntgenfysik(Swepub:uu)janerube
(author)
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Carravetta, V.
(author)
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Ågren, HansKTH,Teoretisk kemi(Swepub:kth)u1l2s96v
(author)
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Feifel, RaimundUppsala universitet,Mjukröntgenfysik(Swepub:uu)rfe32143
(author)
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Uppsala universitetMjukröntgenfysik
(creator_code:org_t)
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In:Journal of Chemical Physics: AIP Publishing133:9, s. 94305-0021-96061089-7690
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Niskanen, Johann ...
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Hedin, Lage
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Eland, John H. D ...
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Linusson, Per
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Karlsson, Leif
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Carravetta, V.
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Ågren, Hans
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NATURAL SCIENCES
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Stockholm University
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