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  • Andersson, Egil,1981-Uppsala universitet,Mjukröntgenfysik (author)

Core-valence double photoionization of the CS2 molecule

  • Article/chapterEnglish2010

Publisher, publication year, extent ...

  • AIP Publishing,2010
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:su-50299
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-50299URI
  • https://doi.org/10.1063/1.3469812DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-26693URI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-122570URI

Supplementary language notes

  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • authorCount :10
  • QC 20101130
  • Double photoionization spectra of the CS2 molecule have been recorded using the TOF-PEPECO technique in combination with synchrotron radiation at the photon energies h nu=220, 230, 240, 243, and 362.7 eV. The spectra were recorded in the S 2p and C 1s inner-shell ionization regions and reflect dicationic states formed out of one inner-shell vacancy and one vacancy in the valence region. MCSCF calculations were performed to model the energies of the dicationic states. The spectra associated with a S 2p vacancy are well structured and have been interpreted in some detail by comparison to conventional S 2p and valence photoelectron spectra. The lowest inner-shell-valence dicationic state is observed at the vertical double ionization energy 188.45 eV and is associated with a (2p(3/2))(-1)(2 pi(g))(-1) double vacancy. The spectrum connected to the C 1s vacancy shows a distinct line at 310.8 eV, accompanied by additional broad features at higher double ionization energies. This line is associated with a (C 1s)(-1)(2 pi(g))(-1) double vacancy. (C-) 2010 American Institute of Physics. [doi: 10.1063/1.3469812]

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  • Niskanen, JohannesKTH,Teoretisk kemi(Swepub:kth)u1ylv8dn (author)
  • Hedin, LageUppsala universitet,Mjukröntgenfysik(Swepub:uu)lahed765 (author)
  • Eland, John H. D.Uppsala universitet,Mjukröntgenfysik(Swepub:uu)johel911 (author)
  • Linusson, PerStockholms universitet,Fysikum(Swepub:su)peli6361 (author)
  • Karlsson, LeifUppsala universitet,Mjukröntgenfysik(Swepub:uu)leifkarl (author)
  • Rubensson, Jan-ErikUppsala universitet,Mjukröntgenfysik(Swepub:uu)janerube (author)
  • Carravetta, V. (author)
  • Ågren, HansKTH,Teoretisk kemi(Swepub:kth)u1l2s96v (author)
  • Feifel, RaimundUppsala universitet,Mjukröntgenfysik(Swepub:uu)rfe32143 (author)
  • Uppsala universitetMjukröntgenfysik (creator_code:org_t)

Related titles

  • In:Journal of Chemical Physics: AIP Publishing133:9, s. 94305-0021-96061089-7690

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