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Copper(I) O,O '-dia...
Copper(I) O,O '-dialkyldithiophosphate clusters : EXAFS, NMR and X-ray diffraction studies
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Rusanova, Daniela (author)
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- Christensen, K. E. (author)
- Stockholms universitet,Avdelningen för strukturkemi,Structural Chemistry, Stockholm University
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- Persson, I. (author)
- Department of Chemistry, Swedish University of Agricultural Sciences
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- Pike, K. J. (author)
- ANSTO NMR Facility, Institute of Materials and Engineering Science, Menai
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- Antzutkin, Oleg (author)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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- Zou, X. (author)
- Stockholms universitet,Avdelningen för strukturkemi,Structural Chemistry, Stockholm University
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- Dupree, R. (author)
- Department of Physics, Warwick University, Coventry
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Forsling, Willis (author)
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(creator_code:org_t)
- 2007-03-20
- 2007
- English.
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In: Journal of coordination chemistry (Print). - : Informa UK Limited. - 0095-8972 .- 1029-0389. ; 60:5, s. 517-525
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Subject headings
Close
- Copper K- edge EXAFS data for six polycrystalline cubic cluster compounds, {Cu-8[ S2P(OR)(2)](6)(mu(8)- S)} with R= Et, Pr-n, Pr-i, Bu-n, Bu-i and Am-i, show that the architecture of their Cu-8(S2P)(2)S cores is fairly rigid and independent of both length and branching of the alkyl chain, and that the structure of the cluster is maintained in acetone solution. Solid- state P-31 CP-MAS and static Cu-65 NMR data for {Cu-8[S2P(O-n Pr)(2)] 6(mu(8)- S)} and {Cu-8[S2P(OEt)(2)](6) mu(8)- S)} show similarities in the icosahedral O,O'- dialkyldithiophosphate shells and in the `cubic' copper cores in these cluster compounds. The crystal structure of {Cu-8[S2P(O-n Pr)(2)](6) (mu(8)- S)} was resolved using single- crystal X- ray diffraction.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- copper(I) O
- O '-dialkyldithiophosphate clusters
- EXAFS
- NMR
- X-ray structure
- Chemistry
- Kemi
- Chemistry of Interfaces
Publication and Content Type
- ref (subject category)
- art (subject category)
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