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Investigation into the vibrational yield of OH products in the OH plus H plus H channel arising from the dissociative recombination of H3O+

Zhaunerchyk, Vitali (author)
Stockholms universitet,Fysikum
Geppert, Wolf D. (author)
Stockholms universitet,Fysikum
Rosen, Stefan (author)
Stockholms universitet,Fysikum
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Vigren, Erik (author)
Stockholms universitet,Fysikum
Hamberg, Mathias (author)
Stockholms universitet,Fysikum
Kaminska, Magdalena (author)
Kashperka, Iryna (author)
Stockholms universitet,Fysikum
af Ugglas, Magnus (author)
Stockholms universitet,Fysikum
Semaniak, Jacek (author)
Larsson, Mats (author)
Stockholms universitet,Fysikum
Thomas, Richard D. (author)
Stockholms universitet,Fysikum
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 (creator_code:org_t)
AIP Publishing, 2009
2009
English.
In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 130:21, s. 214302-
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The vibrational population of the hydroxyl radical, OH, formed in the OH+H+H channel arising from the dissociative recombination of the hydronium ion, H3O+, has been investigated at the storage ring CRYRING using a position-sensitive imaging detector. Analysis shows that the OH fragments are predominantly produced in the v=0 and v=1 states with almost equal probabilities. This observation is in disagreement with earlier FALP experiments, which reported OH(v=0) as the dominant product. Possible explanations for this difference are discussed.

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

dissociation
free radicals
hydrogen compounds
ion recombination
oxygen compounds
positive ions
vibrational states
Physics
Fysik

Publication and Content Type

ref (subject category)
art (subject category)

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