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Hot Water from Cold. The Dissociative Recombination of Water Cluster Ions

Thomas, R. D. (author)
Stockholms universitet,Fysikum
Zhaunerchyk, Vitali (author)
Stockholms universitet,Fysikum
Hellberg, Fredrik (author)
Stockholms universitet,Fysikum
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Ehlerding, Anneli (author)
Stockholms universitet,Fysikum
Geppert, Wolf D. (author)
Stockholms universitet,Fysikum
Bahati, E. (author)
Bannister, M. E. (author)
Fogle, M. R. (author)
Vane, C. R. (author)
Petrignani, A. (author)
Andersson, P. U. (author)
Ojekull, J. (author)
Pettersson, J. B. C. (author)
van der Zande, W. J. (author)
Larsson, M. (author)
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 (creator_code:org_t)
2010-02-11
2010
English.
In: Journal of Physical Chemistry A. - : American Chemical Society (ACS). - 1089-5639 .- 1520-5215. ; 114:14, s. 4843-4846
  • Journal article (peer-reviewed)
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  • Dissociative recombination of the Zundel cation D(5)O(2)(+) almost exclusively produces D + 2 D(2)O with a maximum kinetic energy release of 5.1 eV. An imaging technique is used to investigate the distribution of the available reaction energy among these products. Analysis shows that as much as 4 eV can be stored internally by the molecular fragments, with a preference for producing highly excited molecular fragments, and that the deuteron shows a nonrandom distribution of kinetic energies. A possible mechanism and the implications for these observations are addressed.

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