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Quantifying apatite formation and cation leaching from mesoporous bioactive glasses in vitro : a SEM, solid-state NMR and powder XRD study
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- Gunawidjaja, Philips N. (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
- Izquierdo-Barba, Isabel (author)
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- Mathew, Renny (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Garcia, Ana (author)
- Arcos, Daniel (author)
- Vallet-Regi, Maria (author)
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- (creator_code:org_t)
- Royal Society of Chemistry (RSC), 2012
- 2012
- English.
- In: Journal of Materials Chemistry. - : Royal Society of Chemistry (RSC). - 0959-9428 .- 1364-5501. ; 22:15, s. 7214-7223
- Journal article (peer-reviewed)
Abstract
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- By employing solid-state nuclear magnetic resonance (NMR) spectroscopy, powder X-ray diffraction (PXRD), and scanning electron microscopy coupled with energy-dispersive X-ray (EDX) spectroscopy, we compare the biomimetic growth of calcium hydroxyapatite (HA) from an ordered mesoporous bioactive glass (MBG) in simulated body fluid (SBF) and buffered water solutions. For the latter medium, we also examine the effects of using two different MBG concentrations. We evaluate the predicting powers of PXRD and P-31 NMR for directly quantifying the relative amounts of biomimetic amorphous calcium phosphate (ACP) and HA: we observe a very good agreement between the two analytical techniques. Thanks to their mesoporous channel system, fluids readily penetrate throughout sub-mm sized MBG grains, as evidenced by EDX. The latter revealed distinct element-mappings across the material after its exposure to SBF compared to water. Under our in vitro conditions involving relatively high MBG-loadings in the solutions, the HA formation reduces in SBF relative to buffered water, particularly for increasing MBG concentration. These features stem from a high [Ca2+]/[PO43-] ratio resulting in the fluid medium, which retards the HA crystallization by inducing a rapid ACP precipitation and an accompanying depletion of phosphate ions in the solution. This has bearings on the design of bioactivity comparisons of bioglasses exhibiting significantly different cation compositions.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
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- ref (subject category)
- art (subject category)
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- Edén, Mattias
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