Search: onr:"swepub:oai:DiVA.org:su-79887" >
Electrophilic Trifl...
Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes
-
- Janson, Pär G. (author)
- Stockholms universitet,Institutionen för organisk kemi
-
- Ghoneim, Ibrahim (author)
- Stockholms universitet,Institutionen för organisk kemi
-
- Ilchenko, Nadia O. (author)
- Stockholms universitet,Institutionen för organisk kemi
-
show more...
-
- Szabó, Kálmán J. (author)
- Stockholms universitet,Institutionen för organisk kemi
-
show less...
-
(creator_code:org_t)
- 2012-05-21
- 2012
- English.
-
In: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 14:11, s. 2882-2885
- Related links:
-
https://doi.org/10.1...
-
show more...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- Regio- and stereoselective Cu-catalyzed addition of the above hypervalent iodine reagent to alkynes and alkenes was achieved. In the presence of Cul, the reaction is suitable to perform trifluoromethyl-benzoyloxylation and trifluoromethyl-halogenation of alkenes and alkynes. Electron-donating substituents accelerate the process, and alkenes react faster than alkynes emphasizing the electrophilic character of the addition reaction.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- organisk kemi
- Organic Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database