Search: onr:"swepub:oai:DiVA.org:su-89753" >
Cs10H[Ga3H8]3 :
Cs10H[Ga3H8]3 : A Hydrogenous Zintl Phase Containing Propane-Like Polyanions [Ga3H8]3- and Interstitial Hydrogen
-
- Fahlquist, Henrik, 1983- (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
-
- Noréus, Dag (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
-
(creator_code:org_t)
- 2013-06-05
- 2013
- English.
-
In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 52:12, s. 7125-7129
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- The hydrogenous Zintl-phase Cs10H[Ga3H8](3) containing propane-like polyanions [Ga3H(D)(8)](3-) was successfully synthesized by direct hydrogenation of a 1:1 Cs/Ga metal mixture and characterized by powder X-ray and neutron diffraction. The charge of the polyanions is balanced by two different species of cations, hydrogen-centered octahedra [H(D)Cs-6](5+) and isolated Cs+. The structure crystallizes in the hexagonal space group P6(3)/mcm (193) with the cell parameters a = 11.1108(3) angstrom, c = 18.2149(5) angstrom, Z = 2.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- Metal hydrides
- Polyanionic
- X-ray powder diffraction
- Neutron Powder diffraction
- Solid state synthesis
- Structural Chemistry
- strukturkemi
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database