Co-immobilization of an Enzyme and a Metal into the Compartments of Mesoporous Silica for Cooperative Tandem Catalysis: An Artificial Metalloenzyme

Co-immobilization of an Enzyme and a Metal into the Compartments of Mesoporous Silica for Cooperative Tandem Catalysis : An Artificial Metalloenzyme

AuthorCount: 7;
Surpassing nature: A hybrid catalyst in which Candida antarctica lipase B and a nanopalladium species are co-immobilized into the compartments of mesoporous silica is presented. The metal nanoparticles and the enzyme are in close proximity to one another in the cavities of the support. The catalyst mimics a metalloenzyme and was used for dynamic kinetic resolution of a primary amine in high yield and excellent enantioselectivity.

Johnston, Eric V.Stockholms universitet,Institutionen för organisk kemi(Swepub:su)erjo0102 (author)
Verho, Oscar,1986-Stockholms universitet,Institutionen för organisk kemi(Swepub:su)osve3912 (author)
Gustafson, Karl P. J.Stockholms universitet,Institutionen för organisk kemi(Swepub:su)kagu6294 (author)
Shakeri, MozaffarStockholms universitet,Institutionen för organisk kemi (author)
Tai, Cheuk-WaiStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)ctai (author)
Bäckvall, Jan-E.Stockholms universitet,Institutionen för organisk kemi(Swepub:su)backv (author)
Stockholms universitetInstitutionen för organisk kemi (creator_code:org_t)

In:Angewandte Chemie International Edition: Wiley52:52, s. 14006-140101433-78511521-3773

By the author/editor: Engström, Karin; Johnston, Eric V ...; Verho, Oscar, 19 ...; Gustafson, Karl ...; Shakeri, Mozaffa ...; Tai, Cheuk-Wai; show more...; Bäckvall, Jan-E.; show less...

About the subject

NATURAL SCIENCES: NATURAL SCIENCES; and Chemical Science ...; and Organic Chemistr ...

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