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The influence of ca...
The influence of catalyst amount and Pd loading on the H2O2 synthesis from hydrogen and oxygen
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Gemo, Nicola (author)
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Sterchele, Stefano (author)
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- Biasi, Pierdomenico (author)
- Umeå universitet,Kemiska institutionen,Department of Chemical Engineering, Åbo Akademi University, Biskopsgatan 8, Åbo-Turku, Finland
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Centomo, Paolo (author)
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Canu, Paolo (author)
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Zecca, Marco (author)
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- Shchukarev, Andrey (author)
- Umeå universitet,Kemiska institutionen
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Kordas, Krisztian (author)
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Salmi, Tapio Olavi (author)
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- Mikkola, Jyri-Pekka (author)
- Umeå universitet,Kemiska institutionen,Department of Chemical Engineering, Åbo Akademi University, Biskopsgatan 8, Åbo-Turku, Finland
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(creator_code:org_t)
- 2015
- 2015
- English.
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In: Catalysis Science & Technology. - : Royal Society of Chemistry (RSC). - 2044-4753 .- 2044-4761. ; 5:7, s. 3545-3555
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Palladium catalysts with an active metal content from 0.3 to 5.0 wt.% and supported on a strongly acidic, macroporous resin were prepared by ion-exchange/reduction method. H2O2 direct synthesis was carried out in the absence of promoters (acids and halides). The total Pd amount in the reacting environment was varied by changing A) the catalyst concentration in the slurry and B) the Pd content of the catalyst. In both cases, smaller amounts of the active metal enhance the selectivity towards H2O2, at any H-2 conversion, with option B) better than A). In case A), the Pd(II)/Pd(0) molar ratio (XPS) in the spent catalysts was found to decrease at lower catalyst Pd content. With these catalysts and this experimental set-up the dynamic H-2(1)/Pd molar ratio, the metal loading and the metal particle size were the key factors controlling the selectivity, which reached 57% at 60% H-2 conversion, and 80% at lower conversion.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Gemo, Nicola
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Sterchele, Stefa ...
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Biasi, Pierdomen ...
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Centomo, Paolo
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Canu, Paolo
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Zecca, Marco
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show more...
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Shchukarev, Andr ...
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Kordas, Krisztia ...
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Salmi, Tapio Ola ...
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Mikkola, Jyri-Pe ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Materials Chemis ...
- Articles in the publication
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Catalysis Scienc ...
- By the university
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Umeå University