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Low-temperature phase transformation in NaBH4 under pressure

Sundqvist, Bertil (author)
Umeå universitet,Institutionen för fysik
Andersson, Ove (author)
Umeå universitet,Institutionen för fysik
 (creator_code:org_t)
2006
2006
English.
In: Physical Review B. - 1098-0121. ; 73:9, s. 092102-
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The pressure-temperature structural phase diagram of NaBH4 has been mapped by thermal conductivitymeasurements below room temperature and up to 2 GPa. The critical transition temperature for the transformationfrom the low-temperature tetragonal structure to the room temperature cubic one increases from near190 K at zero pressure to about 235 K at 2 GPa. The thermal conductivity data are consistent with theorder-disorder character of the transition.

Subject headings

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

Keyword

Hydride
hydrogen storage
NaBH4
high pressure
phase diagram
phase transition
orientational ordering transition
thermal conductivity
tetragonal
cubic
order-disorder
Condensed matter physics
Kondenserade materiens fysik

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